Charities, along with some Survey's and Political calls, are exempt from the DNC, however, they can still get into trouble for not placing you on a internal DNC when asked, you can also check your states laws in regards. Some states do not allow them to call on their state DNC laws which can differ from the federal.
I have had repeated calls from this number. Yesterday is came at 8:20 AM. The latest at night was 8:45. I think they are telemarketers. They never leave a message.